Oxidation of disulfides by 4-electron transfer to O2: A Ru(bpy)32+-catalyzed photo-oxidation system for selective formation of polythioethers

Kimihisa Yamamoto, Kenichi Oyaizu, Shintaro Kobayashi, Eishun Tsuchida*

*この研究の対応する著者

研究成果: Article査読

2 被引用数 (Scopus)

抄録

Tris(2,2′-bipyridine)ruthenium(II) chloride catalyzed the photo-oxidative polymerization of diaryl disulfides by O2, by which poly(thioarylene)s were efficiently produced. The polymerization proceeded through the electrophilic reaction of the sulfonium cation which was produced selectively by the photo-redox system.

本文言語English
ページ(範囲)407-408
ページ数2
ジャーナルPhosphorus, Sulfur and Silicon and Related Elements
120-121
DOI
出版ステータスPublished - 1997

ASJC Scopus subject areas

  • 生化学
  • 有機化学
  • 無機化学

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