TY - JOUR
T1 - Oxidative cleavage of 4-methylcatechol with a Cu complex bound to poly(styrene-CO-4-vinylpyridine)
AU - Nishide, Hiroyuki
AU - Minakata, T.
AU - Tsuchida, E.
PY - 1982
Y1 - 1982
N2 - The oxidative cleavage of 4-methylcatechol with pyridine-Cu complex to give the monomethyl ester of cis,cis-muconic acid was studied. The obtained yield and kinetic parameters indicated that benzene is a good solvent for the cleavage reaction. A Cu complex bound to a benzene-soluble poly(styrene-co-4-vinylpyridine) was also found to be effective for the cleavage, giving the muconate in ca. 80% yield, σ-Phenylene-diamine was also oxidatively cleaved with the polymer-Cu complex in benzene to give cis,cis-mucononitrile.
AB - The oxidative cleavage of 4-methylcatechol with pyridine-Cu complex to give the monomethyl ester of cis,cis-muconic acid was studied. The obtained yield and kinetic parameters indicated that benzene is a good solvent for the cleavage reaction. A Cu complex bound to a benzene-soluble poly(styrene-co-4-vinylpyridine) was also found to be effective for the cleavage, giving the muconate in ca. 80% yield, σ-Phenylene-diamine was also oxidatively cleaved with the polymer-Cu complex in benzene to give cis,cis-mucononitrile.
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U2 - 10.1016/0304-5102(82)80025-4
DO - 10.1016/0304-5102(82)80025-4
M3 - Article
AN - SCOPUS:41449083950
SN - 0304-5102
VL - 15
SP - 327
EP - 335
JO - Journal of Molecular Catalysis
JF - Journal of Molecular Catalysis
IS - 3
ER -