Oxidative Polymerization of 2,6-Dimethylphenol to Form Poly(2,6-dimethyl-1,4-phenyleneoxide) in Water

Kei Saito; Takahiro Tago; Toru Masuyama; Hiroyuki Nishide

doi:10.1002/anie.200352764

Oxidative Polymerization of 2,6-Dimethylphenol to Form Poly(2,6-dimethyl-1,4-phenyleneoxide) in Water

Kei Saito, Takahiro Tago, Toru Masuyama, Hiroyuki Nishide^*

^*この研究の対応する著者

理工学術院総合研究所

研究成果: Article › 査読

67 被引用数 (Scopus)

抄録

Green polymerization: The simple stirring of 2,6-dimethylphenol with an excess of oxidant or a catalytic amount of a copper complex in an alkaline aqueous solution yields poly (2,6-dimethyl-1,4-phenyleneoxide), a commercially important polymer (see scheme). The formed polymer was easily separated as an off-white powder by filtration.

本文言語	English
ページ（範囲）	730-733
ページ数	4
ジャーナル	Angewandte Chemie - International Edition
巻	43
号	6
DOI	https://doi.org/10.1002/anie.200352764
出版ステータス	Published - 2004 1月 30

ASJC Scopus subject areas

化学 (全般)

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10.1002/anie.200352764

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AU - Nishide, Hiroyuki

PY - 2004/1/30

Y1 - 2004/1/30

N2 - Green polymerization: The simple stirring of 2,6-dimethylphenol with an excess of oxidant or a catalytic amount of a copper complex in an alkaline aqueous solution yields poly (2,6-dimethyl-1,4-phenyleneoxide), a commercially important polymer (see scheme). The formed polymer was easily separated as an off-white powder by filtration.

AB - Green polymerization: The simple stirring of 2,6-dimethylphenol with an excess of oxidant or a catalytic amount of a copper complex in an alkaline aqueous solution yields poly (2,6-dimethyl-1,4-phenyleneoxide), a commercially important polymer (see scheme). The formed polymer was easily separated as an off-white powder by filtration.

KW - Green chemistry

KW - Oxidation

KW - Polymerization

KW - Radicals

KW - Water chemistry

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Oxidative Polymerization of 2,6-Dimethylphenol to Form Poly(2,6-dimethyl-1,4-phenyleneoxide) in Water

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