TY - JOUR
T1 - Oxygen binding to the iron-copper cofacial diporphyrin derivative embedded in polymer film
AU - Tsuchida, Eishun
AU - Nishide, Hiroyuki
AU - Takane, Minoru
AU - Yoshioka, Hiroshi
AU - Wang, Shen guo
PY - 1985
Y1 - 1985
N2 - An iron-copper cofacial diporphyrin derivative was synthesized from 3,8,13,18-tetramethyl-2,12-diethylporphine-7, 17-diacetic acid. Its iron(II)-imidazole complex formed the oxyen adduct reversibly when it was embedded in synthetic polymer film. Oxygen binding affinity (P 1 2(O2)) and P 1 2(O2)/P 1 2(CO) were reduced to ca. 30 mm Hg and ca. 400, respectively, and they were not affected by polymer species.
AB - An iron-copper cofacial diporphyrin derivative was synthesized from 3,8,13,18-tetramethyl-2,12-diethylporphine-7, 17-diacetic acid. Its iron(II)-imidazole complex formed the oxyen adduct reversibly when it was embedded in synthetic polymer film. Oxygen binding affinity (P 1 2(O2)) and P 1 2(O2)/P 1 2(CO) were reduced to ca. 30 mm Hg and ca. 400, respectively, and they were not affected by polymer species.
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U2 - 10.1016/0162-0134(85)83006-3
DO - 10.1016/0162-0134(85)83006-3
M3 - Article
AN - SCOPUS:46549096870
SN - 0162-0134
VL - 25
SP - 43
EP - 49
JO - Journal of Inorganic Biochemistry
JF - Journal of Inorganic Biochemistry
IS - 1
ER -