TY - JOUR
T1 - OXYGEN EVOLUTION REACTION ON COMPOSITE COBALT BORIDES.
AU - Osaka, Tetsuya
AU - Iwase, Yoshio
AU - Kitayama, Hiroshi
AU - Ichino, Toshihiro
PY - 1983
Y1 - 1983
N2 - The oxygen evolution reaction on cobalt borides and composite cobalt borides was investigated in a 6 m KOH solution (1 m equals 1 mol dm** minus **3) using the factor of the magnetic properties. In the system of cobalt borides (Co:B equals 3:1) prepared at various sintering temperatures, the boride having a higher saturation magnetization revealed a higher activity of the oxygen evolution reaction. In the system of composite cobalt borides which have various magnetic moments, mu //B, a clear correlation between the activity of the oxygen evolution reaction and the saturation magnetization (or magnetic moment, mu //B) was observed for several composite cobalt boride species (i. e. , Co-Fe-B, Co-Ni-B, Co-Mn-B, and Co-B). Among the composite cobalt boride species, the cobalt iron boride (Co:Fe:B equals 1:2:1) sintered at 450 degree C showed the highest activity of oxygen evolution reaction in a 6 m KOH solution.
AB - The oxygen evolution reaction on cobalt borides and composite cobalt borides was investigated in a 6 m KOH solution (1 m equals 1 mol dm** minus **3) using the factor of the magnetic properties. In the system of cobalt borides (Co:B equals 3:1) prepared at various sintering temperatures, the boride having a higher saturation magnetization revealed a higher activity of the oxygen evolution reaction. In the system of composite cobalt borides which have various magnetic moments, mu //B, a clear correlation between the activity of the oxygen evolution reaction and the saturation magnetization (or magnetic moment, mu //B) was observed for several composite cobalt boride species (i. e. , Co-Fe-B, Co-Ni-B, Co-Mn-B, and Co-B). Among the composite cobalt boride species, the cobalt iron boride (Co:Fe:B equals 1:2:1) sintered at 450 degree C showed the highest activity of oxygen evolution reaction in a 6 m KOH solution.
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U2 - 10.1246/bcsj.56.2106
DO - 10.1246/bcsj.56.2106
M3 - Article
AN - SCOPUS:0020500215
SN - 0009-2673
VL - 56
SP - 2106
EP - 2111
JO - Bulletin of the Chemical Society of Japan
JF - Bulletin of the Chemical Society of Japan
IS - 7
ER -