TY - JOUR
T1 - Oxygenation Behaviour of the Porphine-Porphinatoiron Complex
AU - Wang, Shen Guo
AU - Nishide, Hiroyuki
AU - Tsuchida, Eishun
PY - 1985
Y1 - 1985
N2 - Porphine-porphinatoiron (II) [1] was synthesized from 3, 8,13,18-tetramethyl-2,12-diethyl-porphine-7,17-diacetic acid. The complex with imidazole was in a 5-coordinate and high-spin form due to steric effect of the capped porphine. The oxygen adduct of [1] was formed below 0°C, and the life time of the oxygen adduct was longer than that of the corresponding porphinatoiron(II) under the same conditions.
AB - Porphine-porphinatoiron (II) [1] was synthesized from 3, 8,13,18-tetramethyl-2,12-diethyl-porphine-7,17-diacetic acid. The complex with imidazole was in a 5-coordinate and high-spin form due to steric effect of the capped porphine. The oxygen adduct of [1] was formed below 0°C, and the life time of the oxygen adduct was longer than that of the corresponding porphinatoiron(II) under the same conditions.
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U2 - 10.1246/nikkashi.1985.182
DO - 10.1246/nikkashi.1985.182
M3 - Article
AN - SCOPUS:85008585648
SN - 0369-4577
VL - 1985
SP - 182
EP - 184
JO - Nippon Kagaku Kaishi / Chemical Society of Japan - Chemistry and Industrial Chemistry Journal
JF - Nippon Kagaku Kaishi / Chemical Society of Japan - Chemistry and Industrial Chemistry Journal
IS - 2
ER -