抄録
A palladium-catalyzed carbothiolation via the reaction of a σ-alkyl palladium intermediate with a TIPS thioether is described. It was found that the use of Cs2CO3, (IPr)Pd(allyl)Cl, and a TIPS thioether was key to obtaining alkyl aryl and dialkyl sulfides in high yield through the reaction of a σ-alkyl palladium intermediate. The developed reaction is applicable to a wide range of substrates and thiols.
本文言語 | English |
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ページ(範囲) | 8280-8284 |
ページ数 | 5 |
ジャーナル | Organic Letters |
巻 | 21 |
号 | 20 |
DOI | |
出版ステータス | Published - 2019 10月 18 |
ASJC Scopus subject areas
- 生化学
- 物理化学および理論化学
- 有機化学