Photoinduced Catalytic Organic-Hydride Transfer to CO2 Mediated with Ruthenium Complexes as NAD+/NADH Redox Couple Models**

Yusuke Kinoshita; Nagisa Deromachi; Takashi Kajiwara; Take aki Koizumi; Susumu Kitagawa; Hitoshi Tamiaki; Koji Tanaka

doi:10.1002/cssc.202300032

Photoinduced Catalytic Organic-Hydride Transfer to CO₂ Mediated with Ruthenium Complexes as NAD⁺/NADH Redox Couple Models**

Yusuke Kinoshita^*, Nagisa Deromachi, Takashi Kajiwara, Take aki Koizumi, Susumu Kitagawa, Hitoshi Tamiaki^*, Koji Tanaka^*

^*この研究の対応する著者

研究成果: Article › 査読

3 被引用数 (Scopus)

抄録

The catalytic organic-hydride transfer to CO₂ was first achieved through the photoinduced two-electron reduction of the [Ru(bpy)₂(pbn)]²⁺/[Ru(bpy)₂(pbnHH)]²⁺ (bpy=2,2’-bipyridine, pbn=2-(pyridin-2-yl)benzo[b]-1,5-naphthyridine, and pbnHH=2-(pyridin-2-yl)-5,10-dihydrobenzo[b]-1,5-naphthyridine) redox couple in the presence of 1,3-dimethyl-2-phenyl-2,3-dihydro-1H-benzo[d]imidazole (BIH). The active species for the catalytic hydride transfer to carbon dioxide giving formate is [Ru(bpy)(bpy⋅⁻)(pbnHH)]⁺ formed by one-electron reduction of [Ru(bpy)₂(pbnHH)]²⁺ with BI⋅.

本文言語	English
論文番号	e202300032
ジャーナル	ChemSusChem
巻	16
号	6
DOI	https://doi.org/10.1002/cssc.202300032
出版ステータス	Published - 2023 3月 22
外部発表	はい

ASJC Scopus subject areas

環境化学
化学工学一般
材料科学一般
エネルギー一般

文献へのアクセス

10.1002/cssc.202300032

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引用スタイル

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title = "Photoinduced Catalytic Organic-Hydride Transfer to CO2 Mediated with Ruthenium Complexes as NAD+/NADH Redox Couple Models**",

abstract = "The catalytic organic-hydride transfer to CO2 was first achieved through the photoinduced two-electron reduction of the [Ru(bpy)2(pbn)]2+/[Ru(bpy)2(pbnHH)]2+ (bpy=2,2{\textquoteright}-bipyridine, pbn=2-(pyridin-2-yl)benzo[b]-1,5-naphthyridine, and pbnHH=2-(pyridin-2-yl)-5,10-dihydrobenzo[b]-1,5-naphthyridine) redox couple in the presence of 1,3-dimethyl-2-phenyl-2,3-dihydro-1H-benzo[d]imidazole (BIH). The active species for the catalytic hydride transfer to carbon dioxide giving formate is [Ru(bpy)(bpy⋅−)(pbnHH)]+ formed by one-electron reduction of [Ru(bpy)2(pbnHH)]2+ with BI⋅.",

keywords = "carbon dioxide, formate, hydride transfer, organic hydride, photoreduction, ruthenium complex",

author = "Yusuke Kinoshita and Nagisa Deromachi and Takashi Kajiwara and Koizumi, {Take aki} and Susumu Kitagawa and Hitoshi Tamiaki and Koji Tanaka",

note = "Publisher Copyright: {\textcopyright} 2023 The Authors. ChemSusChem published by Wiley-VCH GmbH.",

year = "2023",

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AU - Kinoshita, Yusuke

AU - Deromachi, Nagisa

AU - Kajiwara, Takashi

AU - Koizumi, Take aki

AU - Kitagawa, Susumu

AU - Tamiaki, Hitoshi

AU - Tanaka, Koji

PY - 2023/3/22

Y1 - 2023/3/22

N2 - The catalytic organic-hydride transfer to CO2 was first achieved through the photoinduced two-electron reduction of the [Ru(bpy)2(pbn)]2+/[Ru(bpy)2(pbnHH)]2+ (bpy=2,2’-bipyridine, pbn=2-(pyridin-2-yl)benzo[b]-1,5-naphthyridine, and pbnHH=2-(pyridin-2-yl)-5,10-dihydrobenzo[b]-1,5-naphthyridine) redox couple in the presence of 1,3-dimethyl-2-phenyl-2,3-dihydro-1H-benzo[d]imidazole (BIH). The active species for the catalytic hydride transfer to carbon dioxide giving formate is [Ru(bpy)(bpy⋅−)(pbnHH)]+ formed by one-electron reduction of [Ru(bpy)2(pbnHH)]2+ with BI⋅.

AB - The catalytic organic-hydride transfer to CO2 was first achieved through the photoinduced two-electron reduction of the [Ru(bpy)2(pbn)]2+/[Ru(bpy)2(pbnHH)]2+ (bpy=2,2’-bipyridine, pbn=2-(pyridin-2-yl)benzo[b]-1,5-naphthyridine, and pbnHH=2-(pyridin-2-yl)-5,10-dihydrobenzo[b]-1,5-naphthyridine) redox couple in the presence of 1,3-dimethyl-2-phenyl-2,3-dihydro-1H-benzo[d]imidazole (BIH). The active species for the catalytic hydride transfer to carbon dioxide giving formate is [Ru(bpy)(bpy⋅−)(pbnHH)]+ formed by one-electron reduction of [Ru(bpy)2(pbnHH)]2+ with BI⋅.

KW - carbon dioxide

KW - formate

KW - hydride transfer

KW - organic hydride

KW - photoreduction

KW - ruthenium complex

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