TY - JOUR
T1 - Preparation, Characterization and Nonlinear Optical Properties of One-Dimensional Tetranuclear Platinum Complex/Alumina Composite Films
AU - Kodzasa, Takehito
AU - Kamata, Toshihide
AU - Matsuda, Hiro
AU - Fukaya, Toshio
AU - Mizukami, Fujio
AU - Matsunami, Jun
AU - Nagai, Yuji
AU - Matsumoto, Kazuko
PY - 1997/1/1
Y1 - 1997/1/1
N2 - The preparation of transparent films consisting of one-dimensional tetranuclear platinum complex and an alumina gel was attempted. Characterization of the composite films obtained was performed by UV-Vis-NIR spectroscopy. From the redox behavior of the complex in films, it was confirmed that the complex maintains the tetranuclear structure in the alumina gel, when the content of the complex is low. However, it seems to turn into another complex with a longer platinum chain, as the content of complex in the gel increases. The third-order nonlinear susceptibility χ(3) values of composite films was estimated from the third harmonic generation (THG) Maker-fringe measurements of this preliminary study.
AB - The preparation of transparent films consisting of one-dimensional tetranuclear platinum complex and an alumina gel was attempted. Characterization of the composite films obtained was performed by UV-Vis-NIR spectroscopy. From the redox behavior of the complex in films, it was confirmed that the complex maintains the tetranuclear structure in the alumina gel, when the content of the complex is low. However, it seems to turn into another complex with a longer platinum chain, as the content of complex in the gel increases. The third-order nonlinear susceptibility χ(3) values of composite films was estimated from the third harmonic generation (THG) Maker-fringe measurements of this preliminary study.
KW - Complex-dispersed alumina film
KW - Nonlinear optical properties
KW - One-dimensional tetranuclear platinum complex
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U2 - 10.1007/BF02436979
DO - 10.1007/BF02436979
M3 - Article
AN - SCOPUS:0030678278
SN - 0928-0707
VL - 8
SP - 1029
EP - 1033
JO - Journal of Sol-Gel Science and Technology
JF - Journal of Sol-Gel Science and Technology
IS - 1-3
ER -