Preparation of poly(1,4‐phenylene)s by electro‐oxidative polymerization

Kenichi Oyaizu; Kimihisa Yamamoto; Toshio Asada; Hiroyuki Nishide; Eishun Tsuchida

doi:10.1002/pat.1995.220060406

Preparation of poly(1,4‐phenylene)s by electro‐oxidative polymerization

Kenichi Oyaizu^*, Kimihisa Yamamoto, Toshio Asada, Hiroyuki Nishide, Eishun Tsuchida

^*この研究の対応する著者

理工学術院総合研究所

研究成果: Article › 査読

1 被引用数 (Scopus)

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The effect of substituents on the electropolymerization of benzene derivatives and the redox properrties of the corresponding polymers were determined using Brown's substituent constants (σ⁺). Electron‐donating groups lower the oxidation potential by which increase in the current efficiency was observed. However, stabilization of the produced cation radicals by the electron‐donating groups resulted in a decrease in the polymerization efficiency. The appropriate values of σ⁺ for the efficient polymerization ranged near −1.5.

本文言語	English
ページ（範囲）	254-257
ページ数	4
ジャーナル	Polymers for Advanced Technologies
巻	6
号	4
DOI	https://doi.org/10.1002/pat.1995.220060406
出版ステータス	Published - 1995

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10.1002/pat.1995.220060406

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abstract = "The effect of substituents on the electropolymerization of benzene derivatives and the redox properrties of the corresponding polymers were determined using Brown's substituent constants (σ+). Electron‐donating groups lower the oxidation potential by which increase in the current efficiency was observed. However, stabilization of the produced cation radicals by the electron‐donating groups resulted in a decrease in the polymerization efficiency. The appropriate values of σ+ for the efficient polymerization ranged near −1.5.",

keywords = "electro‐oxidative polymerization, poly(1,4‐phenylene), substituent effect",

author = "Kenichi Oyaizu and Kimihisa Yamamoto and Toshio Asada and Hiroyuki Nishide and Eishun Tsuchida",

year = "1995",

doi = "10.1002/pat.1995.220060406",

language = "English",

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T1 - Preparation of poly(1,4‐phenylene)s by electro‐oxidative polymerization

AU - Oyaizu, Kenichi

AU - Yamamoto, Kimihisa

AU - Asada, Toshio

AU - Nishide, Hiroyuki

AU - Tsuchida, Eishun

PY - 1995

Y1 - 1995

N2 - The effect of substituents on the electropolymerization of benzene derivatives and the redox properrties of the corresponding polymers were determined using Brown's substituent constants (σ+). Electron‐donating groups lower the oxidation potential by which increase in the current efficiency was observed. However, stabilization of the produced cation radicals by the electron‐donating groups resulted in a decrease in the polymerization efficiency. The appropriate values of σ+ for the efficient polymerization ranged near −1.5.

AB - The effect of substituents on the electropolymerization of benzene derivatives and the redox properrties of the corresponding polymers were determined using Brown's substituent constants (σ+). Electron‐donating groups lower the oxidation potential by which increase in the current efficiency was observed. However, stabilization of the produced cation radicals by the electron‐donating groups resulted in a decrease in the polymerization efficiency. The appropriate values of σ+ for the efficient polymerization ranged near −1.5.

KW - electro‐oxidative polymerization

KW - poly(1,4‐phenylene)

KW - substituent effect

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JO - Polymers for Advanced Technologies

JF - Polymers for Advanced Technologies

IS - 4

ER -

Preparation of poly(1,4‐phenylene)s by electro‐oxidative polymerization

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