Preparation of silyl-functionalized double six-ring (D6R) siloxanes and unique assembly by hydrogen bonding of silanol groups

Naoto Sato; Hiroaki Wada; Kazuyuki Kuroda; Atsushi Shimojima

doi:10.1093/chemle/upad048

Preparation of silyl-functionalized double six-ring (D6R) siloxanes and unique assembly by hydrogen bonding of silanol groups

Naoto Sato, Hiroaki Wada, Kazuyuki Kuroda, Atsushi Shimojima^*

^*この研究の対応する著者

先進理工学部

研究成果: Article › 査読

2 被引用数 (Scopus)

抄録

Cage-type silicate with a double six-ring (D6R) structure is successfully functionalized with dimethylsilyl and dimethylsilanol groups. The dimethylsilanol-functionalized cages are assembled to form a 1D structure through intermolecular hydrogen bonding of the silanol groups between the cages. These results will contribute to the development of a building-block approach for the creation of ordered siloxane-based nanomaterials.

本文言語	English
論文番号	upad048
ジャーナル	Chemistry Letters
巻	53
号	2
DOI	https://doi.org/10.1093/chemle/upad048
出版ステータス	Published - 2024 2月

ASJC Scopus subject areas

化学一般

文献へのアクセス

10.1093/chemle/upad048

他のファイルとリンク

フィンガープリント

「Preparation of silyl-functionalized double six-ring (D6R) siloxanes and unique assembly by hydrogen bonding of silanol groups」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル

@article{66dc6e12e6594f3bb9c7e4e54b57c299,

title = "Preparation of silyl-functionalized double six-ring (D6R) siloxanes and unique assembly by hydrogen bonding of silanol groups",

abstract = "Cage-type silicate with a double six-ring (D6R) structure is successfully functionalized with dimethylsilyl and dimethylsilanol groups. The dimethylsilanol-functionalized cages are assembled to form a 1D structure through intermolecular hydrogen bonding of the silanol groups between the cages. These results will contribute to the development of a building-block approach for the creation of ordered siloxane-based nanomaterials.",

keywords = "hydrogen bond, ordered assembly, silanol, siloxane",

author = "Naoto Sato and Hiroaki Wada and Kazuyuki Kuroda and Atsushi Shimojima",

note = "Publisher Copyright: {\textcopyright} The Author(s) 2023.",

year = "2024",

month = feb,

doi = "10.1093/chemle/upad048",

language = "English",

volume = "53",

journal = "Chemistry Letters",

issn = "0366-7022",

publisher = "Oxford University Press",

number = "2",

}

TY - JOUR

T1 - Preparation of silyl-functionalized double six-ring (D6R) siloxanes and unique assembly by hydrogen bonding of silanol groups

AU - Sato, Naoto

AU - Wada, Hiroaki

AU - Kuroda, Kazuyuki

AU - Shimojima, Atsushi

N1 - Publisher Copyright: © The Author(s) 2023.

PY - 2024/2

Y1 - 2024/2

N2 - Cage-type silicate with a double six-ring (D6R) structure is successfully functionalized with dimethylsilyl and dimethylsilanol groups. The dimethylsilanol-functionalized cages are assembled to form a 1D structure through intermolecular hydrogen bonding of the silanol groups between the cages. These results will contribute to the development of a building-block approach for the creation of ordered siloxane-based nanomaterials.

AB - Cage-type silicate with a double six-ring (D6R) structure is successfully functionalized with dimethylsilyl and dimethylsilanol groups. The dimethylsilanol-functionalized cages are assembled to form a 1D structure through intermolecular hydrogen bonding of the silanol groups between the cages. These results will contribute to the development of a building-block approach for the creation of ordered siloxane-based nanomaterials.

KW - hydrogen bond

KW - ordered assembly

KW - silanol

KW - siloxane

UR - http://www.scopus.com/inward/record.url?scp=85189272544&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85189272544&partnerID=8YFLogxK

U2 - 10.1093/chemle/upad048

DO - 10.1093/chemle/upad048

M3 - Article

AN - SCOPUS:85189272544

SN - 0366-7022

VL - 53

JO - Chemistry Letters

JF - Chemistry Letters

IS - 2

M1 - upad048

ER -