Preparation of α-zirconium phosphate from fluorozirconate and phosphoric acid by liquid-phase deposition

Seiichi Tahara; Yoshie Takakura; Yoshiyuki Sugahara

doi:10.1246/cl.2012.555

Preparation of α-zirconium phosphate from fluorozirconate and phosphoric acid by liquid-phase deposition

Seiichi Tahara, Yoshie Takakura, Yoshiyuki Sugahara^*

^*この研究の対応する著者

先進理工学部

研究成果: Article › 査読

9 被引用数 (Scopus)

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α-Zirconium phosphate (α-ZrP) was prepared by liquid-phase deposition. Boric acid was added to a solution containing [ZrF ₆] ^2- anions, and phosphoric acid dropwise to cause slow decomposition of [ZrF ₆] ^2- and the subsequent reaction with H ₃PO ₄ to form α-ZrP. X-ray diffraction, scanning electron microscopy, solid-state ³¹P nuclear magnetic resonance spectroscopy, infrared spectroscopy, thermogravimetry, and elemental analyses indicate the formation of single-phase α-ZrP.

本文言語	English
ページ（範囲）	555-557
ページ数	3
ジャーナル	Chemistry Letters
巻	41
号	5
DOI	https://doi.org/10.1246/cl.2012.555
出版ステータス	Published - 2012 5月 3

ASJC Scopus subject areas

化学 (全般)

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title = "Preparation of α-zirconium phosphate from fluorozirconate and phosphoric acid by liquid-phase deposition",

abstract = "α-Zirconium phosphate (α-ZrP) was prepared by liquid-phase deposition. Boric acid was added to a solution containing [ZrF 6] 2- anions, and phosphoric acid dropwise to cause slow decomposition of [ZrF 6] 2- and the subsequent reaction with H 3PO 4 to form α-ZrP. X-ray diffraction, scanning electron microscopy, solid-state 31P nuclear magnetic resonance spectroscopy, infrared spectroscopy, thermogravimetry, and elemental analyses indicate the formation of single-phase α-ZrP.",

author = "Seiichi Tahara and Yoshie Takakura and Yoshiyuki Sugahara",

year = "2012",

month = may,

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doi = "10.1246/cl.2012.555",

language = "English",

volume = "41",

pages = "555--557",

journal = "Chemistry Letters",

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T1 - Preparation of α-zirconium phosphate from fluorozirconate and phosphoric acid by liquid-phase deposition

AU - Tahara, Seiichi

AU - Takakura, Yoshie

AU - Sugahara, Yoshiyuki

PY - 2012/5/3

Y1 - 2012/5/3

N2 - α-Zirconium phosphate (α-ZrP) was prepared by liquid-phase deposition. Boric acid was added to a solution containing [ZrF 6] 2- anions, and phosphoric acid dropwise to cause slow decomposition of [ZrF 6] 2- and the subsequent reaction with H 3PO 4 to form α-ZrP. X-ray diffraction, scanning electron microscopy, solid-state 31P nuclear magnetic resonance spectroscopy, infrared spectroscopy, thermogravimetry, and elemental analyses indicate the formation of single-phase α-ZrP.

AB - α-Zirconium phosphate (α-ZrP) was prepared by liquid-phase deposition. Boric acid was added to a solution containing [ZrF 6] 2- anions, and phosphoric acid dropwise to cause slow decomposition of [ZrF 6] 2- and the subsequent reaction with H 3PO 4 to form α-ZrP. X-ray diffraction, scanning electron microscopy, solid-state 31P nuclear magnetic resonance spectroscopy, infrared spectroscopy, thermogravimetry, and elemental analyses indicate the formation of single-phase α-ZrP.

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JO - Chemistry Letters

JF - Chemistry Letters

IS - 5

ER -

Preparation of α-zirconium phosphate from fluorozirconate and phosphoric acid by liquid-phase deposition

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