TY - JOUR
T1 - Pulse radiolysis studies on the transient species of aromatic molecules in chlorinated hydrocarbon solutions
AU - Washio, Masakazu
AU - Tagawa, Seiichi
AU - Furuya, Kazuo
AU - Hayashi, Nariyuki
AU - Tabata, Yoneho
PY - 1989/12/1
Y1 - 1989/12/1
N2 - Pulse radiolysis has been carried out to identify the transient species produced by the pulsed electron irradiation for the several kinds of combination of the solutions of aromatic hydrocarbons (benzene, naphthalene and pyrene) in chlorinated hydrocarbons (CCl4, CHCl3, and CH2Cl2). Charge-transfer complex between aromatic ring and Cl atom has been observed for benzene solutions in above three solvents. Naphthalene monomer and dimer cation radicals have been observed for the solutions in CHCl3 and CH2Cl2. Monomer cation radicals of pyrene has been observed for the solution of pyrene in CCl4, and monomer and dimer cation radicals of pyrene have been observed for the solutions in CHCl3 and CH2Cl2.
AB - Pulse radiolysis has been carried out to identify the transient species produced by the pulsed electron irradiation for the several kinds of combination of the solutions of aromatic hydrocarbons (benzene, naphthalene and pyrene) in chlorinated hydrocarbons (CCl4, CHCl3, and CH2Cl2). Charge-transfer complex between aromatic ring and Cl atom has been observed for benzene solutions in above three solvents. Naphthalene monomer and dimer cation radicals have been observed for the solutions in CHCl3 and CH2Cl2. Monomer cation radicals of pyrene has been observed for the solution of pyrene in CCl4, and monomer and dimer cation radicals of pyrene have been observed for the solutions in CHCl3 and CH2Cl2.
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M3 - Conference article
AN - SCOPUS:0024933073
SN - 0969-806X
VL - 34
SP - 533
EP - 537
JO - Radiation Physics and Chemistry
JF - Radiation Physics and Chemistry
IS - 4
T2 - Proceedings of an International Symposium on Fast Excitation Processes
Y2 - 21 March 1988 through 25 March 1988
ER -