Raman spectra of Langmuir-Blodgett and Langmuir-Schaefer films of polydiacetylene prepared from 10,12-pentacosadiynoic acid

Keisuke Seto, Yoshinobu Hosoi, Yukio Furukawa*

*この研究の対応する著者

研究成果: Article査読

37 被引用数 (Scopus)

抄録

Blue polydiacetylene films were prepared from the Langmuir-Schaefer (LS) and Langmuir-Blodgett (LB) films of the cadmium salt of 10,12-pentacosadiynoic acid, CH3(CH2)11{single bond}C{triple bond, long}C{single bond}C{triple bond, long}C{single bond}(CH2)8COOH, and the C{triple bond, long}C stretching modes of the Raman spectra of the LS and LB films were observed at 2068 and 2079 cm-1, respectively. These wavenumbers appeared to be sensitive to the packing of polymer chains. Most of the progression bands observed in the range of 1332-1182 cm-1 have been assigned to the CH2 wagging modes of the all-trans structure of the (CH2)11CH3 group.

本文言語English
ページ(範囲)328-332
ページ数5
ジャーナルChemical Physics Letters
444
4-6
DOI
出版ステータスPublished - 2007 8月 27

ASJC Scopus subject areas

  • 物理学および天文学一般
  • 物理化学および理論化学

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