A membrane of a cobalt tetraazaporphyrin polymer complex was prepared with a nanometer thickness and used as an oxygen-facilitated transport membrane. Rapid and reversible oxygen binding to the cobalt tetaazaporphyrin complex with a polymeric imidazole ligand was observed at low temperature. Oxygen transport through the membrane was facilitated and a high (oxygen/nitrogen) permselectivity of 28 was obtained.
|ジャーナル||Macromolecular Rapid Communications|
|出版ステータス||Published - 2005 3月 18|
ASJC Scopus subject areas