Reversible stretching of a polymer-supported cobalt-chelate film in response to oxygen

Hiroyuki Nishide; Hiroyuki Mizuma; Eishun Tsuchida; James McBreen

doi:10.1246/bcsj.72.1123

Reversible stretching of a polymer-supported cobalt-chelate film in response to oxygen

Hiroyuki Nishide^*, Hiroyuki Mizuma, Eishun Tsuchida, James McBreen

^*この研究の対応する著者

理工学術院総合研究所

研究成果: Article › 査読

6 被引用数 (Scopus)

抄録

The polymer-supported N,N'-di(salicylidene)ethylenediaminatocobalt(II) [Co(salen)] took up oxygen through 2/1 Co/dioxygen adduct formation. The composite film of the polymer-supported [Co(salen)] and polymer layers reversibly bent under an oxygen and nitrogen atmosphere. The stretching was caused by a structural change in the [Co(salen)] crystal before and after the oxygen-binding, which was analyzed based on the near-IR spectral and density change as well as EXAFS.

本文言語	English
ページ（範囲）	1123-1127
ページ数	5
ジャーナル	Bulletin of the Chemical Society of Japan
巻	72
号	5
DOI	https://doi.org/10.1246/bcsj.72.1123
出版ステータス	Published - 1999 5月

ASJC Scopus subject areas

化学 (全般)

文献へのアクセス

10.1246/bcsj.72.1123

他のファイルとリンク

引用スタイル

@article{43dd12e3f5c0416d8f27288ffc2052a0,

title = "Reversible stretching of a polymer-supported cobalt-chelate film in response to oxygen",

abstract = "The polymer-supported N,N'-di(salicylidene)ethylenediaminatocobalt(II) [Co(salen)] took up oxygen through 2/1 Co/dioxygen adduct formation. The composite film of the polymer-supported [Co(salen)] and polymer layers reversibly bent under an oxygen and nitrogen atmosphere. The stretching was caused by a structural change in the [Co(salen)] crystal before and after the oxygen-binding, which was analyzed based on the near-IR spectral and density change as well as EXAFS.",

author = "Hiroyuki Nishide and Hiroyuki Mizuma and Eishun Tsuchida and James McBreen",

year = "1999",

month = may,

doi = "10.1246/bcsj.72.1123",

language = "English",

volume = "72",

pages = "1123--1127",

journal = "Bulletin of the Chemical Society of Japan",

issn = "0009-2673",

publisher = "Chemical Society of Japan",

number = "5",

}

TY - JOUR

T1 - Reversible stretching of a polymer-supported cobalt-chelate film in response to oxygen

AU - Nishide, Hiroyuki

AU - Mizuma, Hiroyuki

AU - Tsuchida, Eishun

AU - McBreen, James

PY - 1999/5

Y1 - 1999/5

N2 - The polymer-supported N,N'-di(salicylidene)ethylenediaminatocobalt(II) [Co(salen)] took up oxygen through 2/1 Co/dioxygen adduct formation. The composite film of the polymer-supported [Co(salen)] and polymer layers reversibly bent under an oxygen and nitrogen atmosphere. The stretching was caused by a structural change in the [Co(salen)] crystal before and after the oxygen-binding, which was analyzed based on the near-IR spectral and density change as well as EXAFS.

AB - The polymer-supported N,N'-di(salicylidene)ethylenediaminatocobalt(II) [Co(salen)] took up oxygen through 2/1 Co/dioxygen adduct formation. The composite film of the polymer-supported [Co(salen)] and polymer layers reversibly bent under an oxygen and nitrogen atmosphere. The stretching was caused by a structural change in the [Co(salen)] crystal before and after the oxygen-binding, which was analyzed based on the near-IR spectral and density change as well as EXAFS.

UR - http://www.scopus.com/inward/record.url?scp=0032983288&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0032983288&partnerID=8YFLogxK

U2 - 10.1246/bcsj.72.1123

DO - 10.1246/bcsj.72.1123

M3 - Article

AN - SCOPUS:0032983288

SN - 0009-2673

VL - 72

SP - 1123

EP - 1127

JO - Bulletin of the Chemical Society of Japan

JF - Bulletin of the Chemical Society of Japan

IS - 5

ER -

Reversible stretching of a polymer-supported cobalt-chelate film in response to oxygen

抄録

ASJC Scopus subject areas

文献へのアクセス

他のファイルとリンク

フィンガープリント

引用スタイル