@article{7ae7846334204086ab44d7223bd3cec8,
title = "Rh-catalyzed regiodivergent hydrosilylation of acyl aminocyclopropanes controlled by monophosphine ligands",
abstract = "A Rh-catalyzed regiodivergent hydrosilylation of acyl aminocyclopropanes has been developed. Acyl aminocyclopropanes were reacted with hydrosilanes in the presence of Rh catalysts to afford ring-opened hydrosilylated adducts through carbon-carbon (C-C) bond cleavage of the cyclopropane ring. The regioselectivity of the addition of silanes (linear or branched) can be switched by changing the monophosphine ligand. This C-C bond cleavage/hydrosilylation methodology is applicable to the synthesis of silanediol precursors.",
author = "Hiroki Kondo and Kenichiro Itami and Junichiro Yamaguchi",
note = "Funding Information: This work was supported by JSPS KAKENHI Grant No. JP16H01011 and JP16H04148 (to J. Y.), the ERATO program from JST (K. I.), and a JSPS research fellowship for young scientists (to H. K.). ITbM is supported by the World Premier International Research Center (WPI) Initiative, Japan. Publisher Copyright: {\textcopyright} 2017 The Royal Society of Chemistry.",
year = "2017",
doi = "10.1039/c7sc00071e",
language = "English",
volume = "8",
pages = "3799--3803",
journal = "Chemical Science",
issn = "2041-6520",
publisher = "Royal Society of Chemistry",
number = "5",
}