Rhodium complex-catalyzed intramolecular ene-type reaction of allenynes

Takanori Shibata; Yuri Takesue; Sho Kadowaki; Kentaro Takagi

doi:10.1055/s-2003-36804

Rhodium complex-catalyzed intramolecular ene-type reaction of allenynes

Takanori Shibata^*, Yuri Takesue, Sho Kadowaki, Kentaro Takagi

^*この研究の対応する著者

研究成果: Article › 査読

69 被引用数 (Scopus)

抄録

Wilkinson's catalyst [RhCl(PPh₃)₃] catalyzed a cycloisomerization of allenynes which possess geminal methyls on the allene terminus and an intramolecular ene-type reaction proceeded to give various cross-conjugated trienes. Thermal Diels-Alder reaction of the obtained triene was examined to give a bicyclic compound in a high yield.

本文言語	English
ページ（範囲）	268-270
ページ数	3
ジャーナル	Synlett
号	2
DOI	https://doi.org/10.1055/s-2003-36804
出版ステータス	Published - 2003 1月 1
外部発表	はい

ASJC Scopus subject areas

有機化学

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title = "Rhodium complex-catalyzed intramolecular ene-type reaction of allenynes",

abstract = "Wilkinson's catalyst [RhCl(PPh3)3] catalyzed a cycloisomerization of allenynes which possess geminal methyls on the allene terminus and an intramolecular ene-type reaction proceeded to give various cross-conjugated trienes. Thermal Diels-Alder reaction of the obtained triene was examined to give a bicyclic compound in a high yield.",

keywords = "Alkynes, Allenes, Catalysis, Ene reactions, Rhodium",

author = "Takanori Shibata and Yuri Takesue and Sho Kadowaki and Kentaro Takagi",

year = "2003",

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doi = "10.1055/s-2003-36804",

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T1 - Rhodium complex-catalyzed intramolecular ene-type reaction of allenynes

AU - Shibata, Takanori

AU - Takesue, Yuri

AU - Kadowaki, Sho

AU - Takagi, Kentaro

PY - 2003/1/1

Y1 - 2003/1/1

N2 - Wilkinson's catalyst [RhCl(PPh3)3] catalyzed a cycloisomerization of allenynes which possess geminal methyls on the allene terminus and an intramolecular ene-type reaction proceeded to give various cross-conjugated trienes. Thermal Diels-Alder reaction of the obtained triene was examined to give a bicyclic compound in a high yield.

AB - Wilkinson's catalyst [RhCl(PPh3)3] catalyzed a cycloisomerization of allenynes which possess geminal methyls on the allene terminus and an intramolecular ene-type reaction proceeded to give various cross-conjugated trienes. Thermal Diels-Alder reaction of the obtained triene was examined to give a bicyclic compound in a high yield.

KW - Alkynes

KW - Allenes

KW - Catalysis

KW - Ene reactions

KW - Rhodium

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U2 - 10.1055/s-2003-36804

DO - 10.1055/s-2003-36804

M3 - Article

AN - SCOPUS:0037287106

SN - 0936-5214

SP - 268

EP - 270

JO - Synlett

JF - Synlett

IS - 2

ER -

Rhodium complex-catalyzed intramolecular ene-type reaction of allenynes

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