Standard Gibbs energies of formation for AlCl(g) and AlCl2(g) species at temperatures from 600 to 1300 K

M. Numata*, M. Sugiura, A. Fuwa

*この研究の対応する著者

    研究成果: Article査読

    3 被引用数 (Scopus)

    抄録

    The equilibria in the Al(1)-Cl2(g) system have been studied at temperatures from 600 to 1300 K using a transpiration reactor. The equilibria considered were those among Al(s or l)-Al(g)-Cl2(g)-AlCl(g)-AlCl2(g)-AlCl3(g)-Al2Cl6( g). The standard Gibbs energies of formation for the AlCl(g) and AlCl2(g) species at these temperatures have been determined simultaneously, where these subchloride species coexist in appreciable quantities with the AlCl3(g) and Al2Cl6(g) species in the gas phase at these temperatures, as follows: AlCl(g): ΔGf·AlCl·T 0(600-900 K) = -76.6-8.05×10-2T; ΔGf·AlCl·T 0(1000-1300 K) = -91.9-6.41×10-2T AlCl2(g): ΔGf·AlCl(2)·T 0(600-900 K) = -319-3.35×10-2T; ΔGf·AlCl(2)·T 0(1000-1300 K) = -335-1.65×10-2T.

    本文言語English
    ページ(範囲)511-516
    ページ数6
    ジャーナルmaterials transactions, jim
    34
    6
    出版ステータスPublished - 1993 6月

    ASJC Scopus subject areas

    • 工学(全般)

    フィンガープリント

    「Standard Gibbs energies of formation for AlCl(g) and AlCl2(g) species at temperatures from 600 to 1300 K」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

    引用スタイル