Standard Gibbs energies of formation of SiCl2(g) and SiCl3(g) species at 1000 to 1300 K

Masaki Kanamori; Masahito Sugiura; Akio Fuwa

Standard Gibbs energies of formation of SiCl₂(g) and SiCl₃(g) species at 1000 to 1300 K

Masaki Kanamori^*, Masahito Sugiura, Akio Fuwa

^*この研究の対応する著者

研究成果: Article › 査読

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The equilibria in the Si(s)-Cl₂(g) system have been studied at temperature from 1000 to 1300 K using a transpiration reactor. The equilibria are considered among Si(s)-Cl₂(g)-SiCl₂(g)-SiCl₃(g)-SiCl₄(g). The standard Gibbs energies of formation for the species of SiCl₂(g) and SiCl₃(g) species at these temperatures are determined simultaneously, where these subchloride species coexist in appreciable quantities with SiCl₄ in the gas phase at these temperatures, as follows: SiCl₂(g): ΔG°_{f·SiCl(2)·T}(1000-1300 K)=-185.0-2.32×10^-2 T kJ·mol^-1 SiCl₃(g): ΔG°_{f·SiCl(3)·T}(1000-1300 K)=-401.1+3.28×10^-2 T kJ·mol^-1

本文言語	English
ページ（範囲）	156-163
ページ数	8
ジャーナル	Nippon Kinzoku Gakkaishi/Journal of the Japan Institute of Metals
巻	59
号	2
出版ステータス	Published - 1995 2月

ASJC Scopus subject areas

金属および合金

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@article{c118430aa8344c38b83bf196efd1da26,

title = "Standard Gibbs energies of formation of SiCl2(g) and SiCl3(g) species at 1000 to 1300 K",

abstract = "The equilibria in the Si(s)-Cl2(g) system have been studied at temperature from 1000 to 1300 K using a transpiration reactor. The equilibria are considered among Si(s)-Cl2(g)-SiCl2(g)-SiCl3(g)-SiCl4(g). The standard Gibbs energies of formation for the species of SiCl2(g) and SiCl3(g) species at these temperatures are determined simultaneously, where these subchloride species coexist in appreciable quantities with SiCl4 in the gas phase at these temperatures, as follows: SiCl2(g): ΔG°f·SiCl(2)·T(1000-1300 K)=-185.0-2.32×10-2 T kJ·mol-1 SiCl3(g): ΔG°f·SiCl(3)·T(1000-1300 K)=-401.1+3.28×10-2 T kJ·mol-1 ",

author = "Masaki Kanamori and Masahito Sugiura and Akio Fuwa",

year = "1995",

month = feb,

language = "English",

volume = "59",

pages = "156--163",

journal = "Nippon Kinzoku Gakkaishi/Journal of the Japan Institute of Metals",

issn = "0021-4876",

publisher = "Japan Institute of Metals (JIM)",

number = "2",

}

TY - JOUR

T1 - Standard Gibbs energies of formation of SiCl2(g) and SiCl3(g) species at 1000 to 1300 K

AU - Kanamori, Masaki

AU - Sugiura, Masahito

AU - Fuwa, Akio

PY - 1995/2

Y1 - 1995/2

N2 - The equilibria in the Si(s)-Cl2(g) system have been studied at temperature from 1000 to 1300 K using a transpiration reactor. The equilibria are considered among Si(s)-Cl2(g)-SiCl2(g)-SiCl3(g)-SiCl4(g). The standard Gibbs energies of formation for the species of SiCl2(g) and SiCl3(g) species at these temperatures are determined simultaneously, where these subchloride species coexist in appreciable quantities with SiCl4 in the gas phase at these temperatures, as follows: SiCl2(g): ΔG°f·SiCl(2)·T(1000-1300 K)=-185.0-2.32×10-2 T kJ·mol-1 SiCl3(g): ΔG°f·SiCl(3)·T(1000-1300 K)=-401.1+3.28×10-2 T kJ·mol-1

AB - The equilibria in the Si(s)-Cl2(g) system have been studied at temperature from 1000 to 1300 K using a transpiration reactor. The equilibria are considered among Si(s)-Cl2(g)-SiCl2(g)-SiCl3(g)-SiCl4(g). The standard Gibbs energies of formation for the species of SiCl2(g) and SiCl3(g) species at these temperatures are determined simultaneously, where these subchloride species coexist in appreciable quantities with SiCl4 in the gas phase at these temperatures, as follows: SiCl2(g): ΔG°f·SiCl(2)·T(1000-1300 K)=-185.0-2.32×10-2 T kJ·mol-1 SiCl3(g): ΔG°f·SiCl(3)·T(1000-1300 K)=-401.1+3.28×10-2 T kJ·mol-1

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M3 - Article

AN - SCOPUS:0029252190

SN - 0021-4876

VL - 59

SP - 156

EP - 163

JO - Nippon Kinzoku Gakkaishi/Journal of the Japan Institute of Metals

JF - Nippon Kinzoku Gakkaishi/Journal of the Japan Institute of Metals

IS - 2

ER -

Standard Gibbs energies of formation of SiCl2(g) and SiCl3(g) species at 1000 to 1300 K

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ASJC Scopus subject areas

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Standard Gibbs energies of formation of SiCl₂(g) and SiCl₃(g) species at 1000 to 1300 K