TY - JOUR
T1 - Structural transitions in Ba1-xM xBiO3(M = K, Rb)
AU - Nakamura, Shu ichi
AU - Koyama, Yasumasa
AU - Ishimaru, Manabu
N1 - Copyright:
Copyright 2014 Elsevier B.V., All rights reserved.
PY - 1991/12/1
Y1 - 1991/12/1
N2 - Features of structural transitions in Ba1-xK xBiO3 (BKB) and Ba1-xRbxBiO3 (BRB) have been investiga electron diffraction. The analysis of the patterns shows that the crystal system at room temperature changes with respect by means of to x; the cubic system in x > 0.35 and the monoclinic one in 0.1 < x < 0.35. When the temperature is changed the cube to monoclinic transition takes place in 0.1 < x < 0.35. In addition, the softening of a phonon mode at the R point is observed in the cubic structure of x > 0.35.
AB - Features of structural transitions in Ba1-xK xBiO3 (BKB) and Ba1-xRbxBiO3 (BRB) have been investiga electron diffraction. The analysis of the patterns shows that the crystal system at room temperature changes with respect by means of to x; the cubic system in x > 0.35 and the monoclinic one in 0.1 < x < 0.35. When the temperature is changed the cube to monoclinic transition takes place in 0.1 < x < 0.35. In addition, the softening of a phonon mode at the R point is observed in the cubic structure of x > 0.35.
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U2 - 10.1016/0921-4534(91)92150-A
DO - 10.1016/0921-4534(91)92150-A
M3 - Article
AN - SCOPUS:0026373925
SN - 0921-4534
VL - 185-189
SP - 695
EP - 696
JO - Physica C: Superconductivity and its applications
JF - Physica C: Superconductivity and its applications
IS - PART 1
ER -