Styrenic DABCO salt-containing monomers for the synthesis of novel charged polymers

Keren Zhang; Kevin J. Drummey; Nicholas G. Moon; William D. Chiang; Timothy Edward Long

doi:10.1039/c6py00426a

Styrenic DABCO salt-containing monomers for the synthesis of novel charged polymers

Keren Zhang, Kevin J. Drummey, Nicholas G. Moon, William D. Chiang, Timothy Edward Long^*

^*この研究の対応する著者

研究成果: Article › 査読

25 被引用数 (Scopus)

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A facile, two-step synthesis afforded styrenic DABCO salt monomers bearing two cyclic quaternary ammonium cations. Free radical polymerization of the DABCO salt monomers yielded homopolymers and copolymers with n-butyl acrylate. DABCO salt-containing ionomers exhibited superior thermomechanical properties with extended plateau regimes compared to ionomers bearing singly-charged pendant groups.

本文言語	English
ページ（範囲）	3370-3374
ページ数	5
ジャーナル	Polymer Chemistry
巻	7
号	20
DOI	https://doi.org/10.1039/c6py00426a
出版ステータス	Published - 2016 5月 28
外部発表	はい

ASJC Scopus subject areas

バイオエンジニアリング
生化学
生体医工学
ポリマーおよびプラスチック
有機化学

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10.1039/c6py00426a

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abstract = "A facile, two-step synthesis afforded styrenic DABCO salt monomers bearing two cyclic quaternary ammonium cations. Free radical polymerization of the DABCO salt monomers yielded homopolymers and copolymers with n-butyl acrylate. DABCO salt-containing ionomers exhibited superior thermomechanical properties with extended plateau regimes compared to ionomers bearing singly-charged pendant groups.",

author = "Keren Zhang and Drummey, {Kevin J.} and Moon, {Nicholas G.} and Chiang, {William D.} and Long, {Timothy Edward}",

year = "2016",

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doi = "10.1039/c6py00426a",

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AU - Drummey, Kevin J.

AU - Moon, Nicholas G.

AU - Chiang, William D.

AU - Long, Timothy Edward

PY - 2016/5/28

Y1 - 2016/5/28

N2 - A facile, two-step synthesis afforded styrenic DABCO salt monomers bearing two cyclic quaternary ammonium cations. Free radical polymerization of the DABCO salt monomers yielded homopolymers and copolymers with n-butyl acrylate. DABCO salt-containing ionomers exhibited superior thermomechanical properties with extended plateau regimes compared to ionomers bearing singly-charged pendant groups.

AB - A facile, two-step synthesis afforded styrenic DABCO salt monomers bearing two cyclic quaternary ammonium cations. Free radical polymerization of the DABCO salt monomers yielded homopolymers and copolymers with n-butyl acrylate. DABCO salt-containing ionomers exhibited superior thermomechanical properties with extended plateau regimes compared to ionomers bearing singly-charged pendant groups.

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Styrenic DABCO salt-containing monomers for the synthesis of novel charged polymers

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