抄録
Medium size bicyclic ethers of 7-, 8-, and 9-membered rings were synthesized by connection between a hydroxy group on dihydropyranyl ring and a propargylic cation that was stabilized as an acetylene biscobalthexacarbonyl complex under acidic conditions. This cyclization selectively afforded the syntrans bicyclic ring system often seen in marine toxins such as ciguatoxin.
本文言語 | English |
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ページ(範囲) | 473-474 |
ページ数 | 2 |
ジャーナル | Chemistry Letters |
号 | 6 |
DOI | |
出版ステータス | Published - 1996 |
外部発表 | はい |
ASJC Scopus subject areas
- 化学 (全般)