TY - JOUR
T1 - Synthesis and electrochemical properties of bipyrimidine bridged triruthenium complexes
AU - Ohtsu, Hiroyoshi
AU - Kitazume, Jun
AU - Yamaguchi, Tadashi
PY - 2011/8/7
Y1 - 2011/8/7
N2 - A new μ4-bpym-bridged dimer of an oxoacetao-triruthenium complex with carbonyl, [{Ru3O(CH3COO)5(CO)(py)} 2(μ4-bpym)], was synthesized. The complex possesses two stable mixed-valence states associated with Ru3 III,III,II/Ru3III,II,II and Ru3 III,III,III/Ru3III,III,II. The IR-spectroelectrochemistry reveals ν(CO) spectra in five oxidation states, Ru3III,III,III-Ru3III,III,III to Ru3III,II,II-Ru3III,II,II and both the mixed-valence states show a spectrum indicating medium interaction between the Ru3 units.
AB - A new μ4-bpym-bridged dimer of an oxoacetao-triruthenium complex with carbonyl, [{Ru3O(CH3COO)5(CO)(py)} 2(μ4-bpym)], was synthesized. The complex possesses two stable mixed-valence states associated with Ru3 III,III,II/Ru3III,II,II and Ru3 III,III,III/Ru3III,III,II. The IR-spectroelectrochemistry reveals ν(CO) spectra in five oxidation states, Ru3III,III,III-Ru3III,III,III to Ru3III,II,II-Ru3III,II,II and both the mixed-valence states show a spectrum indicating medium interaction between the Ru3 units.
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U2 - 10.1039/c0dt01838d
DO - 10.1039/c0dt01838d
M3 - Article
C2 - 21701734
AN - SCOPUS:80051506934
SN - 1477-9226
VL - 40
SP - 7502
EP - 7504
JO - Dalton Transactions
JF - Dalton Transactions
IS - 29
ER -