Synthesis of a stable 1,2-bis(ferrocenyl)diphosphene

Takahiro Sasamori; Michiyasu Sakagami; Masatoshi Niwa; Heisuke Sakai; Yukio Furukawa; Norihiro Tokitoh

doi:10.1039/c2cc33277a

Synthesis of a stable 1,2-bis(ferrocenyl)diphosphene

Takahiro Sasamori^*, Michiyasu Sakagami, Masatoshi Niwa, Heisuke Sakai, Yukio Furukawa, Norihiro Tokitoh

^*この研究の対応する著者

先進理工学部

研究成果: Article › 査読

24 被引用数 (Scopus)

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The synthesis and characterization of a stable 1,2-bis(ferrocenyl)diphosphene, wherein a P=P π-bond connects two ferrocenyl units will be reported. This represents an unprecedented example for a d–π electron system containing a heavier pnictogen π-spacer group. Stabilization of the highly reactive P=P π-bond was achieved by steric protection using two bulky ferrocenyl moieties.

本文言語	English
ページ（範囲）	8562-8564
ページ数	3
ジャーナル	Chemical Communications
巻	48
号	68
DOI	https://doi.org/10.1039/c2cc33277a
出版ステータス	Published - 2012 7月 30

ASJC Scopus subject areas

触媒
電子材料、光学材料、および磁性材料
セラミックおよび複合材料
化学 (全般)
表面、皮膜および薄膜
金属および合金
材料化学

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AU - Sakagami, Michiyasu

AU - Niwa, Masatoshi

AU - Sakai, Heisuke

AU - Furukawa, Yukio

AU - Tokitoh, Norihiro

PY - 2012/7/30

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AB - The synthesis and characterization of a stable 1,2-bis(ferrocenyl)diphosphene, wherein a P=P π-bond connects two ferrocenyl units will be reported. This represents an unprecedented example for a d–π electron system containing a heavier pnictogen π-spacer group. Stabilization of the highly reactive P=P π-bond was achieved by steric protection using two bulky ferrocenyl moieties.

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Synthesis of a stable 1,2-bis(ferrocenyl)diphosphene

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