Synthesis of multicyclic heterocycles initiated by c-h bond activation along with "rollover" using a Rh(III) catalyst

Takanori Shibata; Satoshi Takayasu

doi:10.1002/hc.21158

Synthesis of multicyclic heterocycles initiated by c-h bond activation along with "rollover" using a Rh(III) catalyst

Takanori Shibata^*, Satoshi Takayasu

^*この研究の対応する著者

先進理工学部

研究成果: Article › 査読

17 被引用数 (Scopus)

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Various multicyclic heterocycles were synthesized via "rollover" as the key pathway using a Rh(III) catalyst with a catalytic amount of sodium pivalate or copper(II) acetate. 3-Alkynyl-2-heteroarylpyridines were transformed into tri- or tetracyclic heterocycles containing two heteroatoms via an intramolecular alkyne insertion. 3-Aryloyl-2-arylpyridines were derived into 4-azafluoren-9-ols via the intramolecular carbonyl insertion.

本文言語	English
ページ（範囲）	379-388
ページ数	10
ジャーナル	Heteroatom Chemistry
巻	25
号	5
DOI	https://doi.org/10.1002/hc.21158
出版ステータス	Published - 2014 11月 1

ASJC Scopus subject areas

化学 (全般)

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10.1002/hc.21158

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AB - Various multicyclic heterocycles were synthesized via "rollover" as the key pathway using a Rh(III) catalyst with a catalytic amount of sodium pivalate or copper(II) acetate. 3-Alkynyl-2-heteroarylpyridines were transformed into tri- or tetracyclic heterocycles containing two heteroatoms via an intramolecular alkyne insertion. 3-Aryloyl-2-arylpyridines were derived into 4-azafluoren-9-ols via the intramolecular carbonyl insertion.

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Synthesis of multicyclic heterocycles initiated by c-h bond activation along with "rollover" using a Rh(III) catalyst

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