抄録
Anodic oxidation of 2,6-disubstituted phenols gave poly(2,6-disubstituted-1,4-phenyleneoxide)s quantitatively by using dichloromethane and tetraethyl ammonium bromide as the solvent and the supporting electrolyte respectively. Phenol was also electro-oxidatively polymerized to yield oligo(1,4-phenyleneoxide) with molecular weight of 1200 approx. 2500. The 2-step polymerization and the polymerization in the presence of bisphenol were carried out to increase the molecular weight of the oligo(phenyleneoxide). The mechanism of the electro-oxidative polymerization was discussed by electrochemical and ESR measurements.
| 本文言語 | English |
|---|---|
| ページ（範囲） | 1081-1096 |
| ページ数 | 16 |
| ジャーナル | Journal of macromolecular science. Chemistry |
| 巻 | A21 |
| 号 | 8-9 |
| 出版ステータス | Published - 1983 7月 |
ASJC Scopus subject areas
- 工学（全般）