Synthesis, structure, and properties of a stable 1,2-dibromodialumane(4) bearing a bulky aryl substituent

Tomohiro Agou; Koichi Nagata; Heisuke Sakai; Yukio Furukawa; Norihiro Tokitoh

doi:10.1021/om300237q

Synthesis, structure, and properties of a stable 1,2-dibromodialumane(4) bearing a bulky aryl substituent

Tomohiro Agou, Koichi Nagata, Heisuke Sakai, Yukio Furukawa, Norihiro Tokitoh^*

^*この研究の対応する著者

先進理工学部

研究成果: Article › 査読

27 被引用数 (Scopus)

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The stable 1,2-dibromodialumane(4) Bbp(Br)Al-Al(Br)Bbp (1; Bbp = 2,6-bis[bis(trimethylsilyl)methyl]phenyl) was synthesized by the reduction of the corresponding dibromoalumane etherate BbpAlBr ₂•OEt ₂ (2). The structure and properties of 1 have been elucidated on the basis of the analyses of spectroscopic and crystallographic data and are supported by DFT calculations.

本文言語	English
ページ（範囲）	3806-3809
ページ数	4
ジャーナル	Organometallics
巻	31
号	9
DOI	https://doi.org/10.1021/om300237q
出版ステータス	Published - 2012 5月 14

ASJC Scopus subject areas

物理化学および理論化学
有機化学
無機化学

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abstract = "The stable 1,2-dibromodialumane(4) Bbp(Br)Al-Al(Br)Bbp (1; Bbp = 2,6-bis[bis(trimethylsilyl)methyl]phenyl) was synthesized by the reduction of the corresponding dibromoalumane etherate BbpAlBr 2•OEt 2 (2). The structure and properties of 1 have been elucidated on the basis of the analyses of spectroscopic and crystallographic data and are supported by DFT calculations.",

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T1 - Synthesis, structure, and properties of a stable 1,2-dibromodialumane(4) bearing a bulky aryl substituent

AU - Agou, Tomohiro

AU - Nagata, Koichi

AU - Sakai, Heisuke

AU - Furukawa, Yukio

AU - Tokitoh, Norihiro

PY - 2012/5/14

Y1 - 2012/5/14

N2 - The stable 1,2-dibromodialumane(4) Bbp(Br)Al-Al(Br)Bbp (1; Bbp = 2,6-bis[bis(trimethylsilyl)methyl]phenyl) was synthesized by the reduction of the corresponding dibromoalumane etherate BbpAlBr 2•OEt 2 (2). The structure and properties of 1 have been elucidated on the basis of the analyses of spectroscopic and crystallographic data and are supported by DFT calculations.

AB - The stable 1,2-dibromodialumane(4) Bbp(Br)Al-Al(Br)Bbp (1; Bbp = 2,6-bis[bis(trimethylsilyl)methyl]phenyl) was synthesized by the reduction of the corresponding dibromoalumane etherate BbpAlBr 2•OEt 2 (2). The structure and properties of 1 have been elucidated on the basis of the analyses of spectroscopic and crystallographic data and are supported by DFT calculations.

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Synthesis, structure, and properties of a stable 1,2-dibromodialumane(4) bearing a bulky aryl substituent

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