The Oxidative Polymerization of 2, 6-Dimethylphenol with a Copper-Pyridine Complex in the Presence of 2, 2-Bis(4-hydroxy-3, 5-dimethylphenyl)propane

Sang Heon Hyun; Toshihiko Maekawa; Hiroyuki Nishide; Eishun Tsuchida

doi:10.1246/nikkashi.1985.238

The Oxidative Polymerization of 2, 6-Dimethylphenol with a Copper-Pyridine Complex in the Presence of 2, 2-Bis(4-hydroxy-3, 5-dimethylphenyl)propane

Sang Heon Hyun, Toshihiko Maekawa, Hiroyuki Nishide, Eishun Tsuchida

理工学術院総合研究所

研究成果: Article › 査読

抄録

2, 6-Dimethylphenol (DMP) was oxidatively polymerized with a copper-pyridine complex in the presence of 2,2-bis(4-hydroxy-3,5-dimethylphenyl)propane (BP). The polymerization gave the poly(2, 6-dimethyl-l, 4-phenylene oxide) having phenolic hydroxyl groups on both the chain ends. From kinetics and spectroscopic analyses of the polymerization, the polymerization mechanism has been disclosed as follows: BP preferentially coordinated to the copper catalyst is activated first, and then reacts with the subsequently activated DMP to give the polymer.

本文言語	English
ページ（範囲）	238-241
ページ数	4
ジャーナル	Nippon Kagaku Kaishi / Chemical Society of Japan - Chemistry and Industrial Chemistry Journal
巻	1985
号	2
DOI	https://doi.org/10.1246/nikkashi.1985.238
出版ステータス	Published - 1985

ASJC Scopus subject areas

化学 (全般)

文献へのアクセス

10.1246/nikkashi.1985.238

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「The Oxidative Polymerization of 2, 6-Dimethylphenol with a Copper-Pyridine Complex in the Presence of 2, 2-Bis(4-hydroxy-3, 5-dimethylphenyl)propane」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル

The Oxidative Polymerization of 2, 6-Dimethylphenol with a Copper-Pyridine Complex in the Presence of 2, 2-Bis(4-hydroxy-3, 5-dimethylphenyl)propane. / Hyun, Sang Heon; Maekawa, Toshihiko; Nishide, Hiroyuki その他.

In: Nippon Kagaku Kaishi / Chemical Society of Japan - Chemistry and Industrial Chemistry Journal, Vol. 1985, No. 2, 1985, p. 238-241.

研究成果: Article › 査読

Hyun, SH, Maekawa, T, Nishide, H & Tsuchida, E 1985, 'The Oxidative Polymerization of 2, 6-Dimethylphenol with a Copper-Pyridine Complex in the Presence of 2, 2-Bis(4-hydroxy-3, 5-dimethylphenyl)propane', Nippon Kagaku Kaishi / Chemical Society of Japan - Chemistry and Industrial Chemistry Journal, vol. 1985, no. 2, pp. 238-241. https://doi.org/10.1246/nikkashi.1985.238

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AB - 2, 6-Dimethylphenol (DMP) was oxidatively polymerized with a copper-pyridine complex in the presence of 2,2-bis(4-hydroxy-3,5-dimethylphenyl)propane (BP). The polymerization gave the poly(2, 6-dimethyl-l, 4-phenylene oxide) having phenolic hydroxyl groups on both the chain ends. From kinetics and spectroscopic analyses of the polymerization, the polymerization mechanism has been disclosed as follows: BP preferentially coordinated to the copper catalyst is activated first, and then reacts with the subsequently activated DMP to give the polymer.

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