The reaction of butatrienolates with aldehydes for the syntheses of α-vinylidene acylsilanes

Takanori Shibata; Kyoko Takami; Yoshikazu Arai; Kyoji Tsachikaina; Shunsuke Maekawa

doi:10.1246/bcsj.77.1937

The reaction of butatrienolates with aldehydes for the syntheses of α-vinylidene acylsilanes

Takanori Shibata^*, Kyoko Takami, Yoshikazu Arai, Kyoji Tsachikaina, Shunsuke Maekawa

^*この研究の対応する著者

先進理工学部

研究成果: Article › 査読

抄録

Lithium butatrienolates were prepared in situ by the 1,4-elimination from 2-butynyl trimethylsilyl ethers along with a retro-Brook rearrangement. The addition reaction of the enolates with the aldehydes afforded β-hydroxy-α-vinyl-idene acylsilanes.

本文言語	English
ページ（範囲）	1937-1938
ページ数	2
ジャーナル	Bulletin of the Chemical Society of Japan
巻	77
号	10
DOI	https://doi.org/10.1246/bcsj.77.1937
出版ステータス	Published - 2004 10月

ASJC Scopus subject areas

化学 (全般)

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10.1246/bcsj.77.1937

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AU - Arai, Yoshikazu

AU - Tsachikaina, Kyoji

AU - Maekawa, Shunsuke

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AB - Lithium butatrienolates were prepared in situ by the 1,4-elimination from 2-butynyl trimethylsilyl ethers along with a retro-Brook rearrangement. The addition reaction of the enolates with the aldehydes afforded β-hydroxy-α-vinyl-idene acylsilanes.

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The reaction of butatrienolates with aldehydes for the syntheses of α-vinylidene acylsilanes

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