Titanosiloxanes consisting of tetrahedrally coordinated Ti cores and branched siloxane cages

Shohei Saito; Kenta Kawamura; Naoto Sato; Takamichi Matsuno; Hiroaki Wada; Kazuyuki Kuroda; Atsushi Shimojima

doi:10.1039/d4dt02848a

Titanosiloxanes consisting of tetrahedrally coordinated Ti cores and branched siloxane cages

Shohei Saito, Kenta Kawamura, Naoto Sato, Takamichi Matsuno, Hiroaki Wada, Kazuyuki Kuroda, Atsushi Shimojima^*

^*この研究の対応する著者

先進理工学部

研究成果: Article › 査読

抄録

Well-defined titanosiloxane molecules with tetrahedrally coordinated Ti centers were synthesized by using monosilanol-functionalized siloxane cages as building blocks. The Ti sites are modified with -OSi(OSi)₃ units, which is analogous to Ti-containing zeolites. Such titanosiloxane molecules are important as models for Ti-containing silica-based catalysts.

本文言語	English
ページ（範囲）	19093-19096
ページ数	4
ジャーナル	Dalton Transactions
巻	53
号	48
DOI	https://doi.org/10.1039/d4dt02848a
出版ステータス	Published - 2024 11月 8

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無機化学

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10.1039/d4dt02848a

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abstract = "Well-defined titanosiloxane molecules with tetrahedrally coordinated Ti centers were synthesized by using monosilanol-functionalized siloxane cages as building blocks. The Ti sites are modified with -OSi(OSi)3 units, which is analogous to Ti-containing zeolites. Such titanosiloxane molecules are important as models for Ti-containing silica-based catalysts.",

author = "Shohei Saito and Kenta Kawamura and Naoto Sato and Takamichi Matsuno and Hiroaki Wada and Kazuyuki Kuroda and Atsushi Shimojima",

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AU - Saito, Shohei

AU - Kawamura, Kenta

AU - Sato, Naoto

AU - Matsuno, Takamichi

AU - Wada, Hiroaki

AU - Kuroda, Kazuyuki

AU - Shimojima, Atsushi

PY - 2024/11/8

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N2 - Well-defined titanosiloxane molecules with tetrahedrally coordinated Ti centers were synthesized by using monosilanol-functionalized siloxane cages as building blocks. The Ti sites are modified with -OSi(OSi)3 units, which is analogous to Ti-containing zeolites. Such titanosiloxane molecules are important as models for Ti-containing silica-based catalysts.

AB - Well-defined titanosiloxane molecules with tetrahedrally coordinated Ti centers were synthesized by using monosilanol-functionalized siloxane cages as building blocks. The Ti sites are modified with -OSi(OSi)3 units, which is analogous to Ti-containing zeolites. Such titanosiloxane molecules are important as models for Ti-containing silica-based catalysts.

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Titanosiloxanes consisting of tetrahedrally coordinated Ti cores and branched siloxane cages

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