抄録
We demonstrate the utilization of cage germoxanes as templates for tuning the pore characteristics of siloxane-based materials. Molecular-scale composites of cage germoxanes and cage siloxanes were prepared by hydrosilylation reactions between SiH- and vinyl-modified cage siloxanes in the presence of vinyl-modified cage germoxanes. Subsequent acid treatments selectively removed the germoxane moiety, resulting in variation in the pore structures. These results contribute to developing a novel method for tuning the pore characteristics of siloxane-based nanoporous materials.
| 本文言語 | English |
|---|---|
| 論文番号 | upae025 |
| ジャーナル | Chemistry Letters |
| 巻 | 53 |
| 号 | 3 |
| DOI | |
| 出版ステータス | Published - 2024 3月 |
ASJC Scopus subject areas
- 化学一般