Water-vapor Sensitive Spin-state Switching in an Iron(III) Complex with Nucleobase Pendants Making Flexible Hydrogen-bonded Networks

Koichi Kagesawa*, Yuki Ichikawa, Hiroaki Iguchi, Brian K. Breedlove, Zhaoyang Li, Masahiro Yamashita, Atsushi Okazawa, Wataru Kosaka, Hitoshi Miyasaka

*この研究の対応する著者

研究成果: Review article査読

9 被引用数 (Scopus)

抄録

Sensitive chemo-switchable magnetic materials operating at room temperature are one of the most potential candidates for future chemical devices. Here, we report a discrete iron(III) complex that exhibits high-spin/low-spin switching, sensitive even to rare water-vapor atmosphere above room temperature. The transformation of the hydrogen-bonded network triggered by water molecules is closely associated with the spin-state changing.

本文言語English
ページ(範囲)1221-1224
ページ数4
ジャーナルChemistry Letters
48
10
DOI
出版ステータスPublished - 2019
外部発表はい

ASJC Scopus subject areas

  • 化学一般

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